Amazing Spider-Man #258 (1984) Venom
Amazing Spider-Man #258 features the story in which Reed Richards of the Fantastic Four discovers that Spidey's black costume is actually an alien symbiote which later infects Eddie Brock and becomes Venom. Human Torch, Black Cat, and Hobgoblin appear. This book is graded 9.6 NM+ with white pages by CBCS. It has excellent color and alignment.