Frank Miller and David Mazzuchelli (of Batman:  Year One fame) team up for an acclaimed 7-issue run in Daredevil beginning with issues #227 - 233.  Daredevil #232 is the sixth chapter.  This issue features the 1st appearance of Nuke.  These issues are widely collected and are an awesome read.  This book is graded 9.6 NM+ with white pages by CGC.